Hi @jriley1414,

This specific option you want for the Excel export feature is unavailable.

Let's take for example the report you stated above, which is the Trial Balance report. There's a single column indent for the account names to differentiate the Total row at the bottom of the report. 

In case you encounter any issues with the export process, keep this article for reference: Fix export to Excel issues in QuickBooks Desktop. 

Post a reply if you need clarification with this process, and I'll get back to you.